Excess Thermodynamic Properties of Binary Liquid System Containing (Cyclic Ether + Octan-1-Ol) At Different Temperature

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Published: Jun 11, 2024
DOI: https://doi.org/10.47191/ijpbms/v4-i6-06
Keywords:
Ultrasonic velocity, adiabatic compressibility, internal pressure, molar volume, intermolecular free length and Redlich-Kister polynomial equation.

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Dhirendra Kumar Sharma
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India.
Suneel Kumar
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India.
Chandra Pal Prajapati
Department of Chemistry, Institute of Basic Science, Bundelkhand University, Jhansi (U.P), India.

Abstract

The ultrasonic velocity (u), density (ρ), and viscosity ( ) for the binary mixture 1,4-Dioxane (1) + Octan-1-ol (2) were measured over the whole composition range at temperature T = (298.15, 303.15 and 305.15) K. The experimental data have been used to calculate excess molar volume (VE), excess adiabatic compressibility ( ), excess viscosity ( ), excess intermolecular free length (  and excess internal pressure (PiE) over the entire composition range. These results have been fitted to the Redlich-Kister polynomial equation. Excess molar volume (VE), excess adiabatic compressibility ( ), excess viscosity ( ), excess intermolecular free length (  and excess internal pressure (PiE) were found to be negative for all temperatures. The results obtained have been discussed and interpreted in terms of the type and nature of the specific intermolecular interactions between the components.


 

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How to Cite
Dhirendra Kumar Sharma, Suneel Kumar, & Chandra Pal Prajapati. (2024). Excess Thermodynamic Properties of Binary Liquid System Containing (Cyclic Ether + Octan-1-Ol) At Different Temperature. International Journal of Pharmaceutical and Bio Medical Science, 4(6), 512–522. https://doi.org/10.47191/ijpbms/v4-i6-06
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Vol. 4 No. 6 (2024): Volume 04 Issue 06 June 2024
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